PhotoChem Match

Images

Photosensitizer

Chemical Formula: C32H24IrN4

Molecular Weight: 656.79

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 420 nm

Excited-state lifetime

τ: 0.31 µs

Excited-state energy

• E_0,0: 2.66 eV

Emission energy

• E_red: -2.05 V vs. SCE

Oxidation energy

• E_ox: 1.25 V vs. SCE

Excited-state reduction potential

• *E_red: 0.61 V vs. SCE

Excited-state oxidation potential

• *E_ox: -1.41 V vs. SCE

References

• Kim, T.; McCarver, S. J.; Lee, C.; MacMillan, D. W. C. Sulfonamidation of Aryl and Heteroaryl Halides through Photosensitized Nickel Catalysis. Angew. Chem. Int. Ed. 2018, 57 (13), 3488–3492.
• Ochola, J. R.; Wolf, M. O. The Effect of Photocatalyst Excited State Lifetime on the Rate of Photoredox Catalysis. Org. Biomol. Chem. 2016, 14 (38), 9088–9092.
• Ladouceur, S.; Zysman‐Colman, E. A Comprehensive Survey of Cationic Iridium(III) Complexes Bearing Nontraditional Ligand Chelation Motifs. Eur. J. Inorg. Chem. 2013, 2013 (17), 2985–3007.