PhotoChem Match

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Photosensitizer

Chemical Formula: C33H21IrN3Na3O9S3

Molecular Weight: 960.9

Absorption maximum wavelength at the lowest-energy absorption peak

λmax: n/a

Excited-state lifetime

τ: 1.62 µs

Excited-state energy

• E_0,0: 2.65 eV

Emission energy

E_red: n/a

Oxidation energy

• E_ox: 0.76 V vs. SCE

Excited-state reduction potential

*E_red: n/a

Excited-state oxidation potential

• *E_ox: -1.89 V vs. SCE

References

• Pfund, B.; Steffen, D. M.; Schreier, M. R.; Bertrams, M.-S.; Ye, C.; Börjesson, K.; Wenger, O. S.; Kerzig, C. UV Light Generation and Challenging Photoreactions Enabled by Upconversion in Water. J. Am. Chem. Soc. 2020, 142 (23), 10468–10476.
• Guo, X.; Okamoto, Y.; Schreier, M. R.; Ward, T. R.; Wenger, O. S. Enantioselective Synthesis of Amines by Combining Photoredox and Enzymatic Catalysis in a Cyclic Reaction Network. Chem. Sci. 2018, 9 (22), 5052–5056.
• Kerzig, C.; Guo, X.; Wenger, O. S. Unexpected Hydrated Electron Source for Preparative Visible-Light Driven Photoredox Catalysis. J. Am. Chem. Soc. 2019, 141 (5), 2122–2127.