PhotoChem Match

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Photosensitizer

Chemical Formula: C32H22F2IrN4

Molecular Weight: 692.77

Absorption maximum wavelength at the lowest-energy absorption peak

λmax: n/a

Excited-state lifetime

τ: 0.186 µs

Excited-state energy

• E_0,0: 2.4 eV

Emission energy

• E_red: -1.26 V vs. SCE

Oxidation energy

• E_ox: 1.4 V vs. SCE

Excited-state reduction potential

• *E_red: 1.14 V vs. SCE

Excited-state oxidation potential

• *E_ox: -1 V vs. SCE

References

• Till, N. A.; Tian, L.; Dong, Z.; Scholes, G. D.; MacMillan, D. W. C. Mechanistic Analysis of Metallaphotoredox C–N Coupling: Photocatalysis Initiates and Perpetuates Ni(I)/Ni(III) Coupling Activity. J. Am. Chem. Soc. 2020, 142 (37), 15830–15841.