PhotoChem Match

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Photosensitizer

Chemical Formula: C45H48IrN3

Molecular Weight: 823.12

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 382 nm

Excited-state lifetime

τ: 1.97 µs

Excited-state energy

• E_0,0: 2.56 eV

Emission energy

• E_red: -2.33 V vs. SCE

Oxidation energy

• E_ox: 0.6 V vs. SCE

Excited-state reduction potential

• *E_red: 0.23 V vs. SCE

Excited-state oxidation potential

• *E_ox: -1.96 V vs. SCE

References

• Nacsa, E. D.; MacMillan, D. W. C. Spin-Center Shift-Enabled Direct Enantioselective α-Benzylation of Aldehydes with Alcohols. J. Am. Chem. Soc. 2018, 140 (9), 3322–3330.
• Dedeian, K.; Djurovich, P. I.; Garces, F. O.; Carlson, G.; Watts, R. J. A New Synthetic Route to the Preparation of a Series of Strong Photoreducing Agents: Fac-Tris-Ortho-Metalated Complexes of Iridium(III) with Substituted 2-Phenylpyridines. Inorg. Chem. 1991, 30 (8), 1685–1687.