PhotoChem Match

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Photosensitizer

Chemical Formula: C8Cl2N2O2

Molecular Weight: 225.93

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 400 nm

Excited-state lifetime

τ: 2.4^t µs

Excited-state energy

• E_0,0: 2.67^t eV
• E_0,0: 3.29^s eV

Emission energy

• E_red: 0.51 V vs. SCE

Oxidation energy

E_ox: n/a

Excited-state reduction potential

• *E_red: 3.18^t V vs. SCE
• *E_red: 3.8^s V vs. SCE

Excited-state oxidation potential

*E_ox: n/a

References

• Ohkubo, K.; Fujimoto, A.; Fukuzumi, S. Visible-Light-Induced Oxygenation of Benzene by the Triplet Excited State of 2,3-Dichloro-5,6-Dicyano-p-Benzoquinone. J. Am. Chem. Soc. 2013, 135 (14), 5368–5371.
• Ohkubo, K.; Hirose, K.; Fukuzumi, S. Solvent-Free One-Step Photochemical Hydroxylation of Benzene Derivatives by the Singlet Excited State of 2,3-Dichloro-5,6-Dicyano-p-Benzoquinone Acting as a Super Oxidant. Chem. – Eur. J. 2015, 21 (7), 2855–2861.