PhotoChem Match

Images

Photosensitizer

Chemical Formula: C36H21F9IrN3

Molecular Weight: 858.79

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 372 nm

Excited-state lifetime

τ: 2.16 µs

Excited-state energy

• E_0,0: 2.76 eV

Emission energy

• E_red: -2.17 V vs. SCE

Oxidation energy

• E_ox: 1.06 V vs. SCE

Excited-state reduction potential

• *E_red: 0.59 V vs. SCE

Excited-state oxidation potential

• *E_ox: -1.7 V vs. SCE

References

• Dedeian, K.; Djurovich, P. I.; Garces, F. O.; Carlson, G.; Watts, R. J. A New Synthetic Route to the Preparation of a Series of Strong Photoreducing Agents: Fac-Tris-Ortho-Metalated Complexes of Iridium(III) with Substituted 2-Phenylpyridines. Inorg. Chem. 1991, 30 (8), 1685–1687.
• Singh, A.; Teegardin, K.; Kelly, M.; Prasad, K. S.; Krishnan, S.; Weaver, J. D. Facile Synthesis and Complete Characterization of Homoleptic and Heteroleptic Cyclometalated Iridium(III) Complexes for Photocatalysis. J. Organomet. Chem. 2015, 776, 51–59.