PhotoChem Match

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Photosensitizer

Chemical Formula: C33H18F6IrN3

Molecular Weight: 762.74

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 378 nm

Excited-state lifetime

τ: 1.6 µs

Excited-state energy

• E_0,0: 2.22 eV

Emission energy

• E_red: -1.87 V vs. SCE

Oxidation energy

• E_ox: 0.94 V vs. SCE

Excited-state reduction potential

• *E_red: 0.36 V vs. SCE

Excited-state oxidation potential

• *E_ox: -1.28 V vs. SCE

References

• Tamayo, A. B.; Alleyne, B. D.; Djurovich, P. I.; Lamansky, S.; Tsyba, I.; Ho, N. N.; Bau, R.; Thompson, M. E. Synthesis and Characterization of Facial and Meridional Tris-Cyclometalated Iridium(III) Complexes. J. Am. Chem. Soc. 2003, 125 (24), 7377–7387.
• Singh, A.; Teegardin, K.; Kelly, M.; Prasad, K. S.; Krishnan, S.; Weaver, J. D. Facile Synthesis and Complete Characterization of Homoleptic and Heteroleptic Cyclometalated Iridium(III) Complexes for Photocatalysis. J. Organomet. Chem. 2015, 776, 51–59.
• Kim, H.; Kim, T.; Lee, D. G.; Roh, S. W.; Lee, C. Nitrogen-Centered Radical-Mediated C–H Imidation of Arenes and Heteroarenes via Visible Light Induced Photocatalysis. Chem. Commun. 2014, 50 (66), 9273–9276.