PhotoChem Match

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Photosensitizer

Chemical Formula: C33H24IrN3

Molecular Weight: 654.79

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 376 nm

Excited-state lifetime

τ: 1.9 µs

Excited-state energy

• E_0,0: 2.58 eV

Emission energy

• E_red: -2.33 V vs. SCE

Oxidation energy

• E_ox: 0.77 V vs. SCE

Excited-state reduction potential

• *E_red: 0.35 V vs. SCE

Excited-state oxidation potential

• *E_ox: -1.88 V vs. SCE

References

• Nacsa, E. D.; MacMillan, D. W. C. Spin-Center Shift-Enabled Direct Enantioselective α-Benzylation of Aldehydes with Alcohols. J. Am. Chem. Soc. 2018, 140 (9), 3322–3330.
• Dedeian, K.; Djurovich, P. I.; Garces, F. O.; Carlson, G.; Watts, R. J. A New Synthetic Route to the Preparation of a Series of Strong Photoreducing Agents: Fac-Tris-Ortho-Metalated Complexes of Iridium(III) with Substituted 2-Phenylpyridines. Inorg. Chem. 1991, 30 (8), 1685–1687.
• Nguyen, J. D.; D’Amato, E. M.; Narayanam, J. M. R.; Stephenson, C. R. J. Engaging Unactivated Alkyl, Alkenyl and Aryl Iodides in Visible-Light-Mediated Free Radical Reactions. Nat. Chem. 2012, 4 (10), 854–859.