PhotoChem Match

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Photosensitizer

Chemical Formula: C24H18N12Ru

Molecular Weight: 575.56

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 443 nm

Excited-state lifetime

τ: 0.74 µs

Excited-state energy

• E_0,0: 2.12 eV

Emission energy

• E_red: -0.8 V vs. SCE

Oxidation energy

• E_ox: 1.86 V vs. SCE

Excited-state reduction potential

• *E_red: 1.45 V vs. SCE

Excited-state oxidation potential

• *E_ox: -0.26 V vs. SCE

References

• Kalyanasundaram, K. Photophysics, Photochemistry and Solar Energy Conversion with Tris(Bipyridyl)Ruthenium(II) and Its Analogues. Coord. Chem. Rev. 1982, 46, 159–244.
• Haga, M.; Dodsworth, E. S.; Eryavec, G.; Seymour, P.; Lever, A. B. P. Luminescence Quenching of the Tris(2,2’-Bipyrazine)Ruthenium(II) Cation and Its Monoprotonated Complex. Inorg. Chem. 1985, 24 (12), 1901–1906.
• Crutchley, R. J.; Lever, A. B. P. Ruthenium(II) Tris(Bipyrazyl) Dication - a New Photocatalyst. J. Am. Chem. Soc. 1980, 102 (23), 7128–7129.