PhotoChem Match

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Photosensitizer

Chemical Formula: C36H36N6Ru

Molecular Weight: 653.8

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 458 nm

Excited-state lifetime

τ: 0.875 µs

Excited-state energy

• E_0,0: 2.06 eV

Emission energy

• E_red: -1.43 V vs. SCE

Oxidation energy

• E_ox: 1.14 V vs. SCE

Excited-state reduction potential

• *E_red: 0.63 V vs. SCE

Excited-state oxidation potential

• *E_ox: -0.92 V vs. SCE

References

• Damrauer, N. H.; Boussie, T. R.; Devenney, M.; McCusker, J. K. Effects of Intraligand Electron Delocalization, Steric Tuning, and Excited-State Vibronic Coupling on the Photophysics of Aryl-Substituted Bipyridyl Complexes of Ru(II). J. Am. Chem. Soc. 1997, 119 (35), 8253–8268.
• Anderson, B. L.; Maher, A. G.; Nava, M.; Lopez, N.; Cummins, C. C.; Nocera, D. G. Ultrafast Photoinduced Electron Transfer from Peroxide Dianion. J. Phys. Chem. B 2015, 119 (24), 7422–7429.