PhotoChem Match

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Photosensitizer

Chemical Formula: C36H24N6Ru

Molecular Weight: 641.7

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 447 nm

Excited-state lifetime

τ: 0.5 µs

Excited-state energy

• E_0,0: 2.18 eV

Emission energy

• E_red: -1.36 V vs. SCE

Oxidation energy

• E_ox: 1.26 V vs. SCE

Excited-state reduction potential

• *E_red: 0.82 V vs. SCE

Excited-state oxidation potential

• *E_ox: -0.87 V vs. SCE

References

• Kalyanasundaram, K. Photophysics, Photochemistry and Solar Energy Conversion with Tris(Bipyridyl)Ruthenium(II) and Its Analogues. Coord. Chem. Rev. 1982, 46, 159–244.
• Young, R. C.; Meyer, T. J.; Whitten, D. G. Electron Transfer Quenching of Excited States of Metal Complexes. J. Am. Chem. Soc. 1976, 98 (1), 286–287.