PhotoChem Match

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Photosensitizer

Chemical Formula: C30H24N6Ru

Molecular Weight: 569.63

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 452 nm

Excited-state lifetime

τ: 1.1 µs

Excited-state energy

• E_0,0: 2.1 eV

Emission energy

• E_red: -1.33 V vs. SCE

Oxidation energy

• E_ox: 1.29 V vs. SCE

Excited-state reduction potential

• *E_red: 0.77 V vs. SCE

Excited-state oxidation potential

• *E_ox: -0.81 V vs. SCE

References

• Prier, C. K.; Rankic, D. A.; MacMillan, D. W. C. Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis. Chem. Rev. 2013, 113 (7), 5322–5363.
• Kalyanasundaram, K. Photophysics, Photochemistry and Solar Energy Conversion with Tris(Bipyridyl)Ruthenium(II) and Its Analogues. Coord. Chem. Rev. 1982, 46, 159–244.
• Juris, A.; Balzani, V.; Belser, P.; Zelewsky, A. von. Characterization of the Excited State Properties of Some New Photosensitizers of the Ruthenium (Polypyridine) Family. Helv. Chim. Acta 1981, 64 (7), 2175–2182.
• Bock, C. R.; Connor, J. A.; Gutierrez, A. R.; Meyer, T. J.; Whitten, D. G.; Sullivan, B. P.; Nagle, J. K. Estimation of Excited-State Redox Potentials by Electron-Transfer Quenching. Application of Electron-Transfer Theory to Excited-State Redox Processes. J. Am. Chem. Soc. 1979, 101 (17), 4815–4824.