PhotoChem Match

Images

Photosensitizer

Chemical Formula: C16H10N4O2S2

Molecular Weight: 354.4

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 448 nm

Excited-state lifetime

τ: n/a

Excited-state energy

• E_0,0: 2.01^t eV

Emission energy

• E_red: -1.45 V vs. SCE

Oxidation energy

• E_ox: 1.37 V vs. SCE

Excited-state reduction potential

• *E_red: 0.91^t V vs. SCE

Excited-state oxidation potential

• *E_ox: -1.17^t V vs. SCE

References

• Hou, M.; Lin, L.; Chai, X.; Zhao, X.; Qiao, B.; Jiang, Z. Enantioselective Photoredox Dehalogenative Protonation. Chem. Sci. 2019, 10 (27), 6629–6634.
• Cao, K.; Tan, S. M.; Lee, R.; Yang, S.; Jia, H.; Zhao, X.; Qiao, B.; Jiang, Z. Catalytic Enantioselective Addition of Prochiral Radicals to Vinylpyridines. J. Am. Chem. Soc. 2019, 141 (13), 5437–5443.
• Zhao, Y.; Zhang, C.; Chin, K. F.; Pytela, O.; Wei, G.; Liu, H.; Bureš, F.; Jiang, Z. Dicyanopyrazine-Derived Push–Pull Chromophores for Highly Efficient Photoredox Catalysis. RSC Adv. 2014, 4 (57), 30062–30067.