PhotoChem Match

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Photosensitizer

Chemical Formula: C48H42N2O4

Molecular Weight: 710.87

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 527 nm

Excited-state lifetime

τ: 0.0038^s µs

Excited-state energy

• E_0,0: 2.34^s eV

Emission energy

• E_red: -0.37 V vs. SCE

Oxidation energy

• E_ox: 1.65 V vs. SCE

Excited-state reduction potential

• *E_red: 1.97^s V vs. SCE

Excited-state oxidation potential

• *E_ox: -0.69^s V vs. SCE

References

• Marchini, M.; Gualandi, A.; Mengozzi, L.; Franchi, P.; Lucarini, M.; Cozzi, P. G.; Balzani, V.; Ceroni, P. Mechanistic Insights into Two-Photon-Driven Photocatalysis in Organic Synthesis. Phys. Chem. Chem. Phys. 2018, 20 (12), 8071–8076.
• Ramanan, C.; Smeigh, A. L.; Anthony, J. E.; Marks, T. J.; Wasielewski, M. R. Competition between Singlet Fission and Charge Separation in Solution-Processed Blend Films of 6,13-Bis(Triisopropylsilylethynyl)Pentacene with Sterically-Encumbered Perylene-3,4:9,10-Bis(Dicarboximide)s. J. Am. Chem. Soc. 2012, 134 (1), 386–397.
• Lee, S. K.; Zu, Y.; Herrmann, A.; Geerts, Y.; Müllen, K.; Bard, A. J. Electrochemistry, Spectroscopy and Electrogenerated Chemiluminescence of Perylene, Terrylene, and Quaterrylene Diimides in Aprotic Solution. J. Am. Chem. Soc. 1999, 121 (14), 3513–3520.
• Ghosh, I.; Ghosh, T.; Bardagi, J. I.; König, B. Reduction of Aryl Halides by Consecutive Visible Light-Induced Electron Transfer Processes. Science 2014, 346 (6210), 725–728.