PhotoChem Match

Images

Photosensitizer

Chemical Formula: C46H31NO

Molecular Weight: 613.76

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 388 nm

Excited-state lifetime

τ: 480^t µs

Excited-state energy

• E_0,0: 2.45^t eV

Emission energy

E_red: n/a

Oxidation energy

• E_ox: 0.65 V vs. SCE

Excited-state reduction potential

*E_red: n/a

Excited-state oxidation potential

• *E_ox: -1.8^t V vs. SCE

References

• Pearson, R. M.; Lim, C.-H.; McCarthy, B. G.; Musgrave, C. B.; Miyake, G. M. Organocatalyzed Atom Transfer Radical Polymerization Using N-Aryl Phenoxazines as Photoredox Catalysts. J. Am. Chem. Soc. 2016, 138 (35), 11399–11407.
• Du, Y.; Pearson, R. M.; Lim, C.-H.; Sartor, S. M.; Ryan, M. D.; Yang, H.; Damrauer, N. H.; Miyake, G. M. Strongly Reducing, Visible-Light Organic Photoredox Catalysts as Sustainable Alternatives to Precious Metals. Chem. – Eur. J. 2017, 23 (46), 10962–10968.
• Buss, B. L.; Beck, L. R.; Miyake, G. M. Synthesis of Star Polymers Using Organocatalyzed Atom Transfer Radical Polymerization through a Core-First Approach. Polym. Chem. 2018, 9 (13), 1658–1665.