PhotoChem Match

Images

Photosensitizer

Chemical Formula: C32H22N2

Molecular Weight: 434.54

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 343 nm

Excited-state lifetime

τ: 4.3^t µs

Excited-state energy

• E_0,0: 1.9^t eV

Emission energy

E_red: n/a

Oxidation energy

• E_ox: 0.21 V vs. SCE

Excited-state reduction potential

*E_red: n/a

Excited-state oxidation potential

• *E_ox: -1.69^t V vs. SCE

References

• Du, Y.; Pearson, R. M.; Lim, C.-H.; Sartor, S. M.; Ryan, M. D.; Yang, H.; Damrauer, N. H.; Miyake, G. M. Strongly Reducing, Visible-Light Organic Photoredox Catalysts as Sustainable Alternatives to Precious Metals. Chem. – Eur. J. 2017, 23 (46), 10962–10968.
• Lim, C.-H.; Ryan, M. D.; McCarthy, B. G.; Theriot, J. C.; Sartor, S. M.; Damrauer, N. H.; Musgrave, C. B.; Miyake, G. M. Intramolecular Charge Transfer and Ion Pairing in N,N-Diaryl Dihydrophenazine Photoredox Catalysts for Efficient Organocatalyzed Atom Transfer Radical Polymerization. J. Am. Chem. Soc. 2017, 139 (1), 348–355.