PhotoChem Match

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Photosensitizer

Chemical Formula: C23H17BF4O

Molecular Weight: 396.19

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 417 nm

Excited-state lifetime

τ: 10^t µs; 0.0029^s µs

Excited-state energy

• E_0,0: 2.3^t eV
• E_0,0: 2.83^s eV

Emission energy

• E_red: -0.32 V vs. SCE

Oxidation energy

E_ox: n/a

Excited-state reduction potential

• *E_red: 1.98^t V vs. SCE
• *E_red: 2.51^s V vs. SCE

Excited-state oxidation potential

*E_ox: n/a

References

• Wang, Y.; Haze, O.; Dinnocenzo, J. P.; Farid, S.; Farid, R. S.; Gould, I. R. Bonded Exciplexes. A New Concept in Photochemical Reactions. J. Org. Chem. 2007, 72 (18), 6970–6981.
• Miranda, M. A.; Garcia, H. 2,4,6-Triphenylpyrylium Tetrafluoroborate as an Electron-Transfer Photosensitizer. Chem. Rev. 1994, 94 (4), 1063–1089.