PhotoChem Match

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Photosensitizer

Chemical Formula: C18H13NS

Molecular Weight: 275.37

Absorption maximum wavelength at the lowest-energy absorption peak

λmax: n/a

Excited-state lifetime

τ₁: 0.00081^a µs

τ₂: 0.0023 µs

Excited-state energy

• E_0,0: 2.4^t eV
• E_0,0: 2.8^s eV

Emission energy

E_red: n/a

Oxidation energy

• E_ox: 0.68 V vs. SCE

Excited-state reduction potential

*E_red: n/a

Excited-state oxidation potential

• *E_ox: -2.1^t V vs. SCE
• *E_ox: -1.7^s V vs. SCE

References

• Romero, N. A.; Nicewicz, D. A. Organic Photoredox Catalysis. Chem. Rev. 2016, 116 (17), 10075–10166.
• Treat, N. J.; Sprafke, H.; Kramer, J. W.; Clark, P. G.; Barton, B. E.; Read de Alaniz, J.; Fors, B. P.; Hawker, C. J. Metal-Free Atom Transfer Radical Polymerization. J. Am. Chem. Soc. 2014, 136 (45), 16096–16101.
• Discekici, E. H.; Treat, N. J.; Poelma, S. O.; Mattson, K. M.; Hudson, Z. M.; Luo, Y.; Hawker, C. J.; Alaniz, J. R. de. A Highly Reducing Metal-Free Photoredox Catalyst: Design and Application in Radical Dehalogenations. Chem. Commun. 2015, 51 (58), 11705–11708.