PhotoChem Match

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Photosensitizer

Chemical Formula: C16H18ClN3S

Molecular Weight: 318.85

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 665 nm

Excited-state lifetime

τ: 77^t µs; 0.001^s µs

Excited-state energy

• E_0,0: 1.85^t eV
• E_0,0: 1.86^s eV

Emission energy

• E_red: -0.3 V vs. SCE

Oxidation energy

• E_ox: 1.13 V vs. SCE

Excited-state reduction potential

• *E_red: 1.55^t V vs. SCE
• *E_red: 1.56^s V vs. SCE

Excited-state oxidation potential

• *E_ox: -0.72^t V vs. SCE
• *E_ox: -0.73^s V vs. SCE

References

• Romero, N. A.; Nicewicz, D. A. Organic Photoredox Catalysis. Chem. Rev. 2016, 116 (17), 10075–10166.
• Shen, T.; Zhao, Z.-G.; Yu, Q.; Xu, H.-J. Photosensitized Reduction of Benzil by Heteroatom-Containing Anthracene Dyes. J. Photochem. Photobiol. Chem. 1989, 47 (2), 203–212.
• I. Alarcon, E.; González-Béjar, M.; Montes-Navajas, P.; Garcia, H.; A. Lissi, E.; C. Scaiano, J. Unexpected Solvent Isotope Effect on the Triplet Lifetime of Methylene Blue Associated to Cucurbit[7]Uril. Photochem. Photobiol. Sci. 2012, 11 (2), 269–273.