Details of C32H18N4

Details of C32H18N4

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Chemical structure

Photosensitizer

Chemical Formula: C32H18N4

Molecular Weight: 458.52

Absorption maximum wavelength at the lowest-energy absorption peak

λmax: 374 nm

Excited-state lifetime

τ: 166 µs

Excited-state energy

E_0,0: 2.63^t eV

Emission energy

E_red: -1.45 V vs. SCE

Oxidation energy

E_ox: 1.47 V vs. SCE

Excited-state reduction potential

*E_red: 1.18^t V vs. SCE

Excited-state oxidation potential

*E_ox: -1.16^t V vs. SCE

References

Ishimatsu, R.; Matsunami, S.; Kasahara, T.; Mizuno, J.; Edura, T.; Adachi, C.; Nakano, K.; Imato, T. Electrogenerated Chemiluminescence of Donor–Acceptor Molecules with Thermally Activated Delayed Fluorescence. Angew. Chem. 2014, 126 (27), 7113–7116.
Rolka, A. B.; Koenig, B. Dearomative Cycloadditions Utilizing an Organic Photosensitizer: An Alternative to Iridium Catalysis. Org. Lett. 2020, 22 (13), 5035–5040.