PhotoChem Match

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Photosensitizer

Chemical Formula: CeCl6

Molecular Weight: 352.82

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 329 nm

Excited-state lifetime

τ: 0.0221 µs

Excited-state energy

• E_0,0: 3.48 eV

Emission energy

E_red: n/a

Oxidation energy

• E_ox: 0.43^c V vs. SCE

Excited-state reduction potential

*E_red: n/a

Excited-state oxidation potential

• *E_ox: -3.05 V vs. SCE

References

• Yin, H.; Jin, Y.; Hertzog, J. E.; Mullane, K. C.; Carroll, P. J.; Manor, B. C.; Anna, J. M.; Schelter, E. J. The Hexachlorocerate(III) Anion: A Potent, Benchtop Stable, and Readily Available Ultraviolet A Photosensitizer for Aryl Chlorides. J. Am. Chem. Soc. 2016, 138 (50), 16266–16273.
• Qiao, Y.; Yang, Q.; Schelter, E. J. Photoinduced Miyaura Borylation by a Rare-Earth-Metal Photoreductant: The Hexachlorocerate(III) Anion. Angew. Chem. Int. Ed. 2018, 57 (34), 10999–11003.