PhotoChem Match

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Photosensitizer

Chemical Formula: C19H50CeN4Si4

Molecular Weight: 587.09

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 429 nm

Excited-state lifetime

τ: 0.117 µs

Excited-state energy

• E_0,0: 2.46 eV

Emission energy

E_red: n/a

Oxidation energy

• E_ox: 0.32^b V vs. SCE

Excited-state reduction potential

*E_red: n/a

Excited-state oxidation potential

• *E_ox: -2.14 V vs. SCE

References

• Yin, H.; Carroll, P. J.; Manor, B. C.; Anna, J. M.; Schelter, E. J. Cerium Photosensitizers: Structure–Function Relationships and Applications in Photocatalytic Aryl Coupling Reactions. J. Am. Chem. Soc. 2016, 138 (18), 5984–5993.
• Qiao, Y.; Cheisson, T.; Manor, B. C.; Carroll, P. J.; Schelter, E. J. A Strategy to Improve the Performance of Cerium(III) Photocatalysts. Chem. Commun. 2019, 55 (28), 4067–4070.