PhotoChem Match

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Photosensitizer

Chemical Formula: C44H30ClN5

Molecular Weight: 664.21

Absorption maximum wavelength at the lowest-energy absorption peak

λmax: n/a

Excited-state lifetime

τ: 0.0115 µs

Excited-state energy

• E_0,0: 2.65 eV

Emission energy

• E_red: -1.41 V vs. SCE

Oxidation energy

• E_ox: 1.31 V vs. SCE

Excited-state reduction potential

• *E_red: 1.24 V vs. SCE

Excited-state oxidation potential

• *E_ox: -1.34 V vs. SCE

References

• Speckmeier, E.; Fischer, T. G.; Zeitler, K. A Toolbox Approach To Construct Broadly Applicable Metal-Free Catalysts for Photoredox Chemistry: Deliberate Tuning of Redox Potentials and Importance of Halogens in Donor–Acceptor Cyanoarenes. J. Am. Chem. Soc. 2018, 140 (45), 15353–15365.