PhotoChem Match

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Photosensitizer

Chemical Formula: C25H68CeN5Si6

Molecular Weight: 747.48

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 423 nm

Excited-state lifetime

τ: 0.067 µs

Excited-state energy

• E_0,0: 2.39 eV

Emission energy

E_red: n/a

Oxidation energy

• E_ox: 0.49^b V vs. SCE

Excited-state reduction potential

*E_red: n/a

Excited-state oxidation potential

• *E_ox: -1.9 V vs. SCE

References

• Yin, H.; Carroll, P. J.; Anna, J. M.; Schelter, E. J. Luminescent Ce(III) Complexes as Stoichiometric and Catalytic Photoreductants for Halogen Atom Abstraction Reactions. J. Am. Chem. Soc. 2015, 137 (29), 9234–9237.
• Qiao, Y.; Schelter, E. J. Lanthanide Photocatalysis. Acc. Chem. Res. 2018, 51 (11), 2926–2936.
• Yin, H.; Carroll, P. J.; Manor, B. C.; Anna, J. M.; Schelter, E. J. Cerium Photosensitizers: Structure–Function Relationships and Applications in Photocatalytic Aryl Coupling Reactions. J. Am. Chem. Soc. 2016, 138 (18), 5984–5993.