PhotoChem Match

Images

Photosensitizer

Chemical Formula: C17H17NO3Pt

Molecular Weight: 478.41

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 420 nm

Excited-state lifetime

τ: 11.6 µs

Excited-state energy

• E_0,0: 2.45 eV

Emission energy

• E_red: -2.2 V vs. SCE

Oxidation energy

• E_ox: 0.52 V vs. SCE

Excited-state reduction potential

• *E_red: 25 V vs. SCE

Excited-state oxidation potential

• *E_ox: -1.93 V vs. SCE

References

• Choi, W. J.; Choi, S.; Ohkubo, K.; Fukuzumi, S.; Cho, E. J.; You, Y. Mechanisms and Applications of Cyclometalated Pt(II) Complexes in Photoredox Catalytic Trifluoromethylation. Chem. Sci. 2015, 6 (2), 1454–1464.