PhotoChem Match

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Photosensitizer

Chemical Formula: C16H13F2NO2Pt

Molecular Weight: 484.37

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 380 nm

Excited-state lifetime

τ: 0.382 µs

Excited-state energy

• E_0,0: 2.73 eV

Emission energy

• E_red: -2.46 V vs. SCE

Oxidation energy

• E_ox: 0.62 V vs. SCE

Excited-state reduction potential

• *E_red: 0.27 V vs. SCE

Excited-state oxidation potential

• *E_ox: -2.11 V vs. SCE

References

• Choi, W. J.; Choi, S.; Ohkubo, K.; Fukuzumi, S.; Cho, E. J.; You, Y. Mechanisms and Applications of Cyclometalated Pt(II) Complexes in Photoredox Catalytic Trifluoromethylation. Chem. Sci. 2015, 6 (2), 1454–1464.