PhotoChem Match

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Photosensitizer

Chemical Formula: C66H28Au2Cl2F48P4

Molecular Weight: 2321.61

Absorption maximum wavelength at the lowest-energy absorption peak

λmax: n/a

Excited-state lifetime

τ: 10000 µs

Excited-state energy

• E_0,0: 2.1 eV

Emission energy

• E_red: -1.65 V vs. SCE

Oxidation energy

• E_ox: 1.41 V vs. SCE

Excited-state reduction potential

• *E_red: 0.45 V vs. SCE

Excited-state oxidation potential

• *E_ox: -0.69 V vs. SCE

References

• McTiernan, C. D.; Morin, M.; McCallum, T.; Scaiano, J. C.; Barriault, L. Polynuclear Gold(I) Complexes in Photoredox Catalysis: Understanding Their Reactivity through Characterization and Kinetic Analysis. Catal. Sci. Technol. 2015, 6 (1), 201–207.