PhotoChem Match

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Photosensitizer

Chemical Formula: C50H44Au2Cl2P4

Molecular Weight: 1233.63

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 320 nm

Excited-state lifetime

τ: 0.85 µs

Excited-state energy

• E_0,0: 2.23 eV

Emission energy

• E_red: -1.63 V vs. SCE

Oxidation energy

• E_ox: 0.7 V vs. SCE

Excited-state reduction potential

• *E_red: 0.6 V vs. SCE

Excited-state oxidation potential

• *E_ox: -1.53 V vs. SCE

References

• McTiernan, C. D.; Morin, M.; McCallum, T.; Scaiano, J. C.; Barriault, L. Polynuclear Gold(I) Complexes in Photoredox Catalysis: Understanding Their Reactivity through Characterization and Kinetic Analysis. Catal. Sci. Technol. 2015, 6 (1), 201–207.
• Nzulu, F.; Telitel, S.; Stoffelbach, F.; Graff, B.; Morlet-Savary, F.; Lalevée, J.; Fensterbank, L.; Goddard, J.-P.; Ollivier, C. A Dinuclear Gold(I) Complex as a Novel Photoredox Catalyst for Light-Induced Atom Transfer Radical Polymerization. Polym. Chem. 2015, 6 (25), 4605–4611.
• McCallum, T.; Barriault, L. Direct Alkylation of Heteroarenes with Unactivated Bromoalkanes Using Photoredox Gold Catalysis. Chem. Sci. 2016, 7 (7), 4754–4758.