PhotoChem Match

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Photosensitizer

Chemical Formula: C42H36CrN6O12

Molecular Weight: 868.78

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 480 nm

Excited-state lifetime

τ: 7.7 µs

Excited-state energy

• E_0,0: 1.7 eV

Emission energy

• E_red: 0.14 V vs. SCE

Oxidation energy

E_ox: n/a

Excited-state reduction potential

• *E_red: 1.84 V vs. SCE

Excited-state oxidation potential

*E_ox: n/a

References

• Stevenson, S. M.; Shores, M. P.; Ferreira, E. M. Photooxidizing Chromium Catalysts for Promoting Radical Cation Cycloadditions. Angew. Chem. Int. Ed. 2015, 54 (22), 6506–6510.
• McDaniel, A. M.; Tseng, H.-W.; Damrauer, N. H.; Shores, M. P. Synthesis and Solution Phase Characterization of Strongly Photooxidizing Heteroleptic Cr(III) Tris-Dipyridyl Complexes. Inorg. Chem. 2010, 49 (17), 7981–7991.