PhotoChem Match

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Photosensitizer

Chemical Formula: C78H102N6W

Molecular Weight: 1307.56

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 465 nm

Excited-state lifetime

τ: 0.122 µs

Excited-state energy

• E_0,0: 2.28 eV

Emission energy

E_red: n/a

Oxidation energy

• E_ox: -0.26^c V vs. SCE

Excited-state reduction potential

*E_red: n/a

Excited-state oxidation potential

• *E_ox: -2.54 V vs. SCE

References

• Sattler, W.; Henling, L. M.; Winkler, J. R.; Gray, H. B. Bespoke Photoreductants: Tungsten Arylisocyanides. J. Am. Chem. Soc. 2015, 137 (3), 1198–1205.
• Sattler, W.; Ener, M. E.; Blakemore, J. D.; Rachford, A. A.; LaBeaume, P. J.; Thackeray, J. W.; Cameron, J. F.; Winkler, J. R.; Gray, H. B. Generation of Powerful Tungsten Reductants by Visible Light Excitation. J. Am. Chem. Soc. 2013, 135 (29), 10614–10617.
• Mann, K. R.; Gray, H. B.; Hammond, G. S. Excited-State Reactivity Patterns of Hexakisarylisocyano Complexes of Chromium(0), Molybdenum(0), and Tungsten(0). J. Am. Chem. Soc. 1977, 99 (1), 306–307.