PhotoChem Match

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Photosensitizer

Chemical Formula: C108H132CrN6

Molecular Weight: 1566.28

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 400 - 600 nm

Excited-state lifetime

τ: 0.0022 µs

Excited-state energy

• E_0,0: 2.05 eV

Emission energy

E_red: n/a

Oxidation energy

• E_ox: 0.18^b V vs. SCE

Excited-state reduction potential

*E_red: n/a

Excited-state oxidation potential

• *E_ox: -1.87 V vs. SCE

References

• Büldt, L. A.; Guo, X.; Vogel, R.; Prescimone, A.; Wenger, O. S. A Tris(Diisocyanide)Chromium(0) Complex Is a Luminescent Analog of Fe(2,2′-Bipyridine)32+. J. Am. Chem. Soc. 2017, 139 (2), 985–992.
• Büldt, L. A.; Wenger, O. S. Chromium(0), Molybdenum(0), and Tungsten(0) Isocyanide Complexes as Luminophores and Photosensitizers with Long-Lived Excited States. Angew. Chem. Int. Ed. 2017, 56 (21), 5676–5682.