PhotoChem Match

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Photosensitizer

Chemical Formula: C72H60MoN6

Molecular Weight: 1105.26

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 350 - 550 nm

Excited-state lifetime

τ: 0.225 µs

Excited-state energy

• E_0,0: 2.2 eV

Emission energy

E_red: n/a

Oxidation energy

• E_ox: -0.02 V vs. SCE

Excited-state reduction potential

*E_red: n/a

Excited-state oxidation potential

• *E_ox: -2.2 V vs. SCE

References

• Herr, P.; Glaser, F.; Büldt, L. A.; Larsen, C. B.; Wenger, O. S. Long-Lived, Strongly Emissive, and Highly Reducing Excited States in Mo(0) Complexes with Chelating Isocyanides. J. Am. Chem. Soc. 2019, 141 (36), 14394–14402.
• Büldt, L. A.; Guo, X.; Prescimone, A.; Wenger, O. S. A Molybdenum(0) Isocyanide Analogue of Ru(2,2′-Bipyridine)32+: A Strong Reductant for Photoredox Catalysis. Angew. Chem. Int. Ed. 2016, 55 (37), 11247–11250.