PhotoChem Match

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Photosensitizer

Chemical Formula: C44H32N4Zr

Molecular Weight: 707.99

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 470 nm

Excited-state lifetime

τ₁: 77 µs

τ₂: 296^c µs

Excited-state energy

• E_0,0: 2.21 eV

Emission energy

• E_red: -1.81^b V vs. SCE

Oxidation energy

E_ox: n/a

Excited-state reduction potential

• *E_red: 0.4 V vs. SCE

Excited-state oxidation potential

*E_ox: n/a

References

• Zhang, Y.; Petersen, J. L.; Milsmann, C. Photochemical C–C Bond Formation in Luminescent Zirconium Complexes with CNN Pincer Ligands. Organometallics 2018, 37 (23), 4488–4499.