PhotoChem Match

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Photosensitizer

Chemical Formula: C54H42N6Zr

Molecular Weight: 866.2

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 528 nm

Excited-state lifetime

τ: 325 µs

Excited-state energy

• E_0,0: 2.09 eV

Emission energy

• E_red: -1.6^a V vs. SCE

Oxidation energy

E_ox: n/a

Excited-state reduction potential

• *E_red: 0.49 V vs. SCE

Excited-state oxidation potential

*E_ox: n/a

References

• Zhang, Y.; Petersen, J. L.; Milsmann, C. A Luminescent Zirconium(IV) Complex as a Molecular Photosensitizer for Visible Light Photoredox Catalysis. J. Am. Chem. Soc. 2016, 138 (40), 13115–13118.
• Zhang, Y.; Lee, T. S.; Petersen, J. L.; Milsmann, C. A Zirconium Photosensitizer with a Long-Lived Excited State: Mechanistic Insight into Photoinduced Single-Electron Transfer. J. Am. Chem. Soc. 2018, 140 (18), 5934–5947.