PhotoChem Match

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Photosensitizer

Chemical Formula: C42H28Br2N6Os

Molecular Weight: 966.77

Absorption maximum wavelength at the lowest-energy absorption peak

λmax: n/a

Excited-state lifetime

τ: 0.2 µs

Excited-state energy

• E_0,0: 1.75 eV

Emission energy

• E_red: -0.86 V vs. SCE

Oxidation energy

• E_ox: 1.04 V vs. SCE

Excited-state reduction potential

• *E_red: 0.89 V vs. SCE

Excited-state oxidation potential

• *E_ox: -0.71 V vs. SCE

References

• Ravetz, B. D.; Tay, N. E. S.; Joe, C. L.; Sezen-Edmonds, M.; Schmidt, M. A.; Tan, Y.; Janey, J. M.; Eastgate, M. D.; Rovis, T. Development of a Platform for Near-Infrared Photoredox Catalysis. ACS Cent. Sci. 2020, 6 (11), 2053–2059.
• Sasaki, Y.; Oshikawa, M.; Bharmoria, P.; Kouno, H.; Hayashi‐Takagi, A.; Sato, M.; Ajioka, I.; Yanai, N.; Kimizuka, N. Near-Infrared Optogenetic Genome Engineering Based on Photon-Upconversion Hydrogels. Angew. Chem. Int. Ed. 2019, 58 (49), 17827–17833.