PhotoChem Match

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Photosensitizer

Chemical Formula: C30H22N6Os

Molecular Weight: 656.78

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 657 nm

Excited-state lifetime

τ: 0.269 µs

Excited-state energy

• E_0,0: 1.77 eV

Emission energy

• E_red: -1.24 V vs. SCE

Oxidation energy

• E_ox: 0.94 V vs. SCE

Excited-state reduction potential

• *E_red: 0.53 V vs. SCE

Excited-state oxidation potential

• *E_ox: -0.83 V vs. SCE

References

• Ravetz, B. D.; Tay, N. E. S.; Joe, C. L.; Sezen-Edmonds, M.; Schmidt, M. A.; Tan, Y.; Janey, J. M.; Eastgate, M. D.; Rovis, T. Development of a Platform for Near-Infrared Photoredox Catalysis. ACS Cent. Sci. 2020, 6 (11), 2053–2059.
• Sauvage, J. P.; Collin, J. P.; Chambron, J. C.; Guillerez, S.; Coudret, C.; Balzani, V.; Barigelletti, F.; De Cola, L.; Flamigni, L. Ruthenium(II) and Osmium(II) Bis(Terpyridine) Complexes in Covalently-Linked Multicomponent Systems: Synthesis, Electrochemical Behavior, Absorption Spectra, and Photochemical and Photophysical Properties. Chem. Rev. 1994, 94 (4), 993–1019.