PhotoChem Match

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Photosensitizer

Chemical Formula: C56H32N6

Molecular Weight: 788.91

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 379 nm

Excited-state lifetime

τ: 5.1^t µs; 0.4^s µs

Excited-state energy

• E_0,0: 2.59^t eV
• E_0,0: 2.64^s eV

Emission energy

• E_red: -1.21 V vs. SCE

Oxidation energy

• E_ox: 1.52 V vs. SCE

Excited-state reduction potential

• *E_red: 1.38^t V vs. SCE
• *E_red: 1.43^s V vs. SCE

Excited-state oxidation potential

• *E_ox: -1.07^t V vs. SCE
• *E_ox: -1.12^s V vs. SCE

References

• Ishimatsu, R.; Matsunami, S.; Kasahara, T.; Mizuno, J.; Edura, T.; Adachi, C.; Nakano, K.; Imato, T. Electrogenerated Chemiluminescence of Donor–Acceptor Molecules with Thermally Activated Delayed Fluorescence. Angew. Chem. 2014, 126 (27), 7113–7116.
• Kretzschmar, A.; Patze, C.; Schwaebel, S. T.; Bunz, U. H. F. Development of Thermally Activated Delayed Fluorescence Materials with Shortened Emissive Lifetimes. J. Org. Chem. 2015, 80 (18), 9126–9131.
• Lu, J.; Pattengale, B.; Liu, Q.; Yang, S.; Shi, W.; Li, S.; Huang, J.; Zhang, J. Donor–Acceptor Fluorophores for Energy-Transfer-Mediated Photocatalysis. J. Am. Chem. Soc. 2018, 140 (42), 13719–13725.
• Saget, T.; König, B. Photocatalytic Synthesis of Polycyclic Indolones. Chem. – Eur. J. 2020, 26 (31), 7004–7007.