PhotoChem Match

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Photosensitizer

Chemical Formula: C66H55CuN2OP2

Molecular Weight: 1017.67

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 387 nm

Excited-state lifetime

τ: n/a

Excited-state energy

• E_0,0: 2.64 eV

Emission energy

• E_red: -1.59 V vs. SCE

Oxidation energy

• E_ox: 1.27 V vs. SCE

Excited-state reduction potential

• *E_red: 1.05 V vs. SCE

Excited-state oxidation potential

• *E_ox: -1.37 V vs. SCE

References

• Zheng, L.; Jiang, Q.; Bao, H.; Zhou, B.; Luo, S.-P.; Jin, H.; Wu, H.; Liu, Y. Tertiary Amines Acting as Alkyl Radical Equivalents Enabled by a P/N Heteroleptic Cu(I) Photosensitizer. Org. Lett. 2020, 22 (22), 8888–8893.