PhotoChem Match

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Photosensitizer

Chemical Formula: C38H26Ar2CuN4O2

Molecular Weight: 714.09

Absorption maximum wavelength at the lowest-energy absorption peak

λmax: n/a

Excited-state lifetime

τ: 0.27 µs

Excited-state energy

• E_0,0: 2.05 eV

Emission energy

E_red: n/a

Oxidation energy

• E_ox: 0.62 V vs. SCE

Excited-state reduction potential

*E_red: n/a

Excited-state oxidation potential

• *E_ox: -1.43 V vs. SCE

References

• Pirtsch, M.; Paria, S.; Matsuno, T.; Isobe, H.; Reiser, O. [Cu(Dap)2Cl] As an Efficient Visible-Light-Driven Photoredox Catalyst in Carbon–Carbon Bond-Forming Reactions. Chem. – Eur. J. 2012, 18 (24), 7336–7340.
• Kern, J.-M.; Sauvage, J.-P. Photoassisted C–C Coupling via Electron Transfer to Benzylic Halides by a Bis(Di-Imine) Copper(I) Complex. J. Chem. Soc. Chem. Commun. 1987, No. 8, 546–548.