PhotoChem Match

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Photosensitizer

Chemical Formula: C39H41ClF4IrN4

Molecular Weight: 869.45

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 436 nm

Excited-state lifetime

τ: 3.05 µs

Excited-state energy

• E_0,0: 2.49 eV

Emission energy

• E_red: -1.19 V vs. SCE

Oxidation energy

• E_ox: 1.88 V vs. SCE

Excited-state reduction potential

• *E_red: 1.3 V vs. SCE

Excited-state oxidation potential

• *E_ox: -0.61 V vs. SCE

References

• Porras, J. A.; Mills, I. N.; Transue, W. J.; Bernhard, S. Highly Fluorinated Ir(III)–2,2′:6′,2″-Terpyridine–Phenylpyridine–X Complexes via Selective C–F Activation: Robust Photocatalysts for Solar Fuel Generation and Photoredox Catalysis. J. Am. Chem. Soc. 2016, 138 (30), 9460–9472.