PhotoChem Match

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Photosensitizer

Chemical Formula: C36H32IrN4

Molecular Weight: 712.9

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 494 nm

Excited-state lifetime

τ: 0.1 µs

Excited-state energy

• E_0,0: 2.46 eV

Emission energy

• E_red: -1.35 V vs. SCE

Oxidation energy

• E_ox: 1.37 V vs. SCE

Excited-state reduction potential

• *E_red: 1.11 V vs. SCE

Excited-state oxidation potential

• *E_ox: -0.87 V vs. SCE

References

• Lam, T. L.; Lai, J.; Annapureddy, R. R.; Xue, M.; Yang, C.; Guan, Y.; Zhou, P.; Chan, S. L.-F. Luminescent Iridium(III) Pyridinium-Derived N-Heterocyclic Carbene Complexes as Versatile Photoredox Catalysts. Inorg. Chem. 2017, 56 (18), 10835–10839.