PhotoChem Match

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Photosensitizer

Chemical Formula: C36H31IrN5

Molecular Weight: 725.9

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 452 nm

Excited-state lifetime

τ: 2.2 µs

Excited-state energy

• E_0,0: 2.72 eV

Emission energy

• E_red: -1.76 V vs. SCE

Oxidation energy

• E_ox: 1.2 V vs. SCE

Excited-state reduction potential

• *E_red: 0.96 V vs. SCE

Excited-state oxidation potential

• *E_ox: -1.52 V vs. SCE

References

• Lam, T. L.; Lai, J.; Annapureddy, R. R.; Xue, M.; Yang, C.; Guan, Y.; Zhou, P.; Chan, S. L.-F. Luminescent Iridium(III) Pyridinium-Derived N-Heterocyclic Carbene Complexes as Versatile Photoredox Catalysts. Inorg. Chem. 2017, 56 (18), 10835–10839.