PhotoChem Match

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Photosensitizer

Chemical Formula: C32H25IrN5

Molecular Weight: 671.8

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 459 nm

Excited-state lifetime

τ: 1 µs

Excited-state energy

• E_0,0: 2.63 eV

Emission energy

• E_red: -1.74 V vs. SCE

Oxidation energy

• E_ox: 1.21 V vs. SCE

Excited-state reduction potential

• *E_red: 0.89 V vs. SCE

Excited-state oxidation potential

• *E_ox: -1.42 V vs. SCE

References

• Lam, T. L.; Lai, J.; Annapureddy, R. R.; Xue, M.; Yang, C.; Guan, Y.; Zhou, P.; Chan, S. L.-F. Luminescent Iridium(III) Pyridinium-Derived N-Heterocyclic Carbene Complexes as Versatile Photoredox Catalysts. Inorg. Chem. 2017, 56 (18), 10835–10839.