PhotoChem Match

Images

Photosensitizer

Chemical Formula: C43H38F6IrN6S2

Molecular Weight: 1009.15

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 447 nm

Excited-state lifetime

τ: 3.2 µs

Excited-state energy

• E_0,0: 2.5 eV

Emission energy

• E_red: -1.52 V vs. SCE

Oxidation energy

• E_ox: 1.23 V vs. SCE

Excited-state reduction potential

• *E_red: 1.03 V vs. SCE

Excited-state oxidation potential

• *E_ox: -1.27 V vs. SCE

References

• Yang, C.; Mehmood, F.; Lam, T. L.; Chan, S. L.-F.; Wu, Y.; Yeung, C.-S.; Guan, X.; Li, K.; Chung, C. Y.-S.; Zhou, C.-Y.; Zou, T.; Che, C.-M. Stable Luminescent Iridium(III) Complexes with Bis(N-Heterocyclic Carbene) Ligands: Photo-Stability, Excited State Properties, Visible-Light-Driven Radical Cyclization and CO2 Reduction, and Cellular Imaging. Chem. Sci. 2016, 7 (5), 3123–3136.