Details of C39H33IrN4

Details of C39H33IrN4

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Chemical structure

Photosensitizer

Chemical Formula: C39H33IrN4

Molecular Weight: 749.94

Absorption maximum wavelength at the lowest-energy absorption peak

λmax: 460 nm

Excited-state lifetime

τ: 0.2 µs

Excited-state energy

E_0,0: 2.4 eV

Emission energy

E_red: n/a

Oxidation energy

E_ox: 0.33 V vs. SCE

Excited-state reduction potential

*E_red: n/a

Excited-state oxidation potential

*E_ox: -2.1 V vs. SCE

References

Shon, J.-H.; Sittel, S.; Teets, T. S. Synthesis and Characterization of Strong Cyclometalated Iridium Photoreductants for Application in Photocatalytic Aryl Bromide Hydrodebromination. ACS Catal. 2019, 9 (9), 8646–8658.
Shon, J.-H.; Teets, T. S. Potent Bis-Cyclometalated Iridium Photoreductants with β-Diketiminate Ancillary Ligands. Inorg. Chem. 2017, 56 (24), 15295–15303.