PhotoChem Match

Images

Photosensitizer

Chemical Formula: C47H49IrN4

Molecular Weight: 862.15

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 485 nm

Excited-state lifetime

τ: 0.15 µs

Excited-state energy

• E_0,0: 2.4 eV

Emission energy

E_red: n/a

Oxidation energy

• E_ox: 0.27 V vs. SCE

Excited-state reduction potential

*E_red: n/a

Excited-state oxidation potential

• *E_ox: -2.1 V vs. SCE

References

• Shon, J.-H.; Sittel, S.; Teets, T. S. Synthesis and Characterization of Strong Cyclometalated Iridium Photoreductants for Application in Photocatalytic Aryl Bromide Hydrodebromination. ACS Catal. 2019, 9 (9), 8646–8658.