PhotoChem Match

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Photosensitizer

Chemical Formula: C38H28IrN4O2S2

Molecular Weight: 829.01

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 437 nm

Excited-state lifetime

τ: 3.9 µs

Excited-state energy

• E_0,0: 2.13 eV

Emission energy

• E_red: -1.43^a V vs. SCE

Oxidation energy

• E_ox: 1.03^a V vs. SCE

Excited-state reduction potential

• *E_red: 0.7 V vs. SCE

Excited-state oxidation potential

• *E_ox: -1.1 V vs. SCE

References

• Takizawa, S.; Shimada, K.; Sato, Y.; Murata, S. Controlling the Excited State and Photosensitizing Property of a 2-(2-Pyridyl)Benzo[b]Thiophene-Based Cationic Iridium Complex through Simple Chemical Modification. Inorg. Chem. 2014, 53 (6), 2983–2995.