PhotoChem Match

Images

Photosensitizer

Chemical Formula: C34H18F10IrN4

Molecular Weight: 864.75

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 412 nm

Excited-state lifetime

τ: 2.28 µs

Excited-state energy

• E_0,0: 2.69 eV

Emission energy

• E_red: -1.37 V vs. SCE

Oxidation energy

• E_ox: 1.69 V vs. SCE

Excited-state reduction potential

• *E_red: 1.32 V vs. SCE

Excited-state oxidation potential

• *E_ox: -1 V vs. SCE

References

• Simons, R. T.; Scott, G. E.; Kanegusuku, A. G.; Roizen, J. L. Photochemically Mediated Nickel-Catalyzed Synthesis of N-(Hetero)Aryl Sulfamides. J. Org. Chem. 2020, 85 (10), 6380–6391.
• Hanss, D.; Freys, J. C.; Bernardinelli, G.; Wenger, O. S. Cyclometalated Iridium(III) Complexes as Photosensitizers for Long-Range Electron Transfer: Occurrence of a Coulomb Barrier. Eur. J. Inorg. Chem. 2009, 2009 (32), 4850–4859.