PhotoChem Match

Images

Photosensitizer

Chemical Formula: C42H34F10IrN4

Molecular Weight: 976.96

Absorption maximum wavelength at the lowest-energy absorption peak

• λmax: 380 nm

Excited-state lifetime

τ: 2.3 µs

Excited-state energy

• E_0,0: 2.9 eV

Emission energy

• E_red: -2.01 V vs. SCE

Oxidation energy

• E_ox: 1.69 V vs. SCE

Excited-state reduction potential

• *E_red: 0.89 V vs. SCE

Excited-state oxidation potential

• *E_ox: -1.21 V vs. SCE

References

• Lu, Z.; Yoon, T. P. Visible Light Photocatalysis of [2+2] Styrene Cycloadditions by Energy Transfer. Angew. Chem. Int. Ed. 2012, 51 (41), 10329–10332.
• Lowry, M. S.; Goldsmith, J. I.; Slinker, J. D.; Rohl, R.; Pascal, R. A.; Malliaras, G. G.; Bernhard, S. Single-Layer Electroluminescent Devices and Photoinduced Hydrogen Production from an Ionic Iridium(III) Complex. Chem. Mater. 2005, 17 (23), 5712–5719.