PhotoChem Match

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Photosensitizer

Chemical Formula: C36H16F16IrN4

Molecular Weight: 1000.74

Absorption maximum wavelength at the lowest-energy absorption peak

λmax: n/a

Excited-state lifetime

τ: 0.28 µs

Excited-state energy

• E_0,0: 2.37 eV

Emission energy

• E_red: -0.69 V vs. SCE

Oxidation energy

• E_ox: 1.94 V vs. SCE

Excited-state reduction potential

• *E_red: 1.68 V vs. SCE

Excited-state oxidation potential

• *E_ox: -0.43 V vs. SCE

References

• Choi, G. J.; Zhu, Q.; Miller, D. C.; Gu, C. J.; Knowles, R. R. Catalytic Alkylation of Remote C-H Bonds Enabled by Proton-Coupled Electron Transfer. Nature 2016, 539 (7628), 268–271.